Robert Filler's Biochemistry Involving Carbon-Fluorine Bonds PDF

By Robert Filler

content material: Reel 1. CA condensates note frequency list.--Reel 2. Key-Letter-in-Context (KLIC) Index of CA condensates phrases (words of frequency more than ten)--Reel three. words from CA condensates record titles; Appendixes A and B.

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A l Wol p o i n t of p a r t i c u l a the b l o o d - b r a i n b a r r i e r very q u i c k l y , and so there i s c o n s i d e r a b l e i n t e r e s t i n t h i s compound f o r b r a i n s c i n t i g r a p h y . ; ACS Symposium Series; American Chemical Society: Washington, DC, 1976. 3 2-Fluoro-L-Histidine: A Histidine Analog Which Inhibits Enzyme Induction DAVID C. KLEIN Section on Physiological Controls, Laboratory of Biomedical Sciences, National Institute of Child Health and Human Development, National Institutes of Health, Bethesda, Md.

Although i t s mechanism of a c t i o n has yet to be e l u c i ­ dated, b i o s y n t h e s i s of ' f a l s e ' phosphorylases or v i r u s - c o a t p r o t ­ e i n s are l o g i c a l p o s s i b i l i t i e s . Small peptides c o n t a i n i n g f l u o r i n e are more r e a d i l y obtained by t o t a l synthesis than by b i o s y n t h e s i s . Thus, t h y r o t r o p i n - r e l e a s ­ i n g f a c t o r (TRF) and l u t e i n i z i n g hormone-releasing f a c t o r (LHRF) have been synthesized with 2- and 4 - f l u o r o h i s t i d i n e as r e p l a c e ­ ments f o r the s i n g l e h i s t i d i n e residues (23).

Proc. Nat. Acad. Sci. USA (1973), 70, 1174. Discussion Q. A. Has there been a check of monitoring on whether C-F cleavage occurs? I assume you r e f e r to s t a b i l i t y i n b i o l o g i c a l systems. The normal pathway f o r h i s t i d i n e degradation i n v o l v e s conversion to urocanic a c i d , and, u l t i m a t e l y , to glutamic a c i d . As I had i n d i c a t e d , 2 - f l u o r o h i s t i d i n e i s a very poor s u b s t r a t e f o r the f i r s t two enzymes i n t h i s pathway; a t the t h i r d s t e p , f l u o ­ r i d e i o n would be r e l e a s e d , together with innocuous degrada­ t i o n products.

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